Carbon Dioxide → Caesium stearate

HRID 576456Notes

Reaction equation

HRID 576456 reaction equation
C([O-])([O-])=O.[Cs+:5].[Cs+].[C:7]([OH:26])(=[O:25])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].C(=O)=O>C(O)CCC>[C:7]([O-:26])(=[O:25])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[Cs+:5]

Participants

5

Reactant 3

HCID 280Carbon DioxideHCID 5281Stearic AcidHCID 10796Cesium carbonate

Product 1

HCID 23720211Caesium stearate

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

A mixture of Cs2CO3 and stearic acid was added to butanol in the ratio 1:2 and kept at reflux temperature until no more CO2 formed. Subsequently, butanol was separated on the rotary evaporator, the residue mixed with ether and aspirated, m.p.:263-269° C.

Workup

  1. customformed
  2. customSubsequently, butanol was separated on the rotary evaporator
  3. additionthe residue mixed with ether

Sources & evidence

ORD record
ord-89685cf973f9440c968721127bded328
Source dataset
uspto-grants-2015_05
Patent number
US09040112B2

Reaction notes

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