Ethyl Acetate → 3-[4-(1-naphthyl)-phenyl]-9-phenyl-9H-carbazole

HRID 579298Notes

Reaction equation

HRID 579298 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:9]=[CH:10][C:11]3[N:12]([C:21]4[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=4)[C:13]4[C:18]([C:19]=3[CH:20]=2)=[CH:17][CH:16]=[CH:15][CH:14]=4)=[CH:4][CH:3]=1.C(O[CH2:31][CH3:32])(=O)C>CCCCCC>[C:7]1([C:2]2[CH:7]=[CH:6][C:5]([C:8]3[CH:9]=[CH:10][C:11]4[N:12]([C:21]5[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=5)[C:13]5[C:18]([C:19]=4[CH:20]=3)=[CH:17][CH:16]=[CH:15][CH:14]=5)=[CH:4][CH:3]=2)[C:31]2[C:32](=[CH:6][CH:5]=[CH:8][CH:20]=2)[CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 8857Ethyl AcetateHCID 513582933-(4-Bromophenyl)-9-phenylcarbazole

Product 1

HCID 666841343-[4-(1-naphthyl)-phenyl]-9-phenyl-9H-carbazole

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The Rf values of the objective substance and 3-(4-bromophenyl)-9-phenyl-9H-carbazole were respectively 0.57 and 0.65, which were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent containing ethyl acetate and hexane in a 1:10 ratio).

Workup

  1. customwhich were obtained by silica gel thin layer chromatography (TLC) (with a developing solvent

Sources & evidence

ORD record
ord-2be7501564954fdd8f67d22f22c01496
Source dataset
uspto-grants-2015_05
Patent number
US09040720B2

Reaction notes

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