3-Nitrobenzaldoxime → 3-Aminobenzylamine

HRID 580088Notes

Reaction equation

HRID 580088 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][CH:12]=1)[CH:7]=[N:8]O)([O-])=O>O1CCCC1>[NH2:1][C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][CH:12]=1)[CH2:7][NH2:8]

Participants

3

Reactant 1

HCID 2191323-Nitrobenzaldoxime

Product 1

HCID 46288313-AminobenzylamineYield 89.2%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The same procedure as in Example 1 was carried out except using m-nitrobenzaldoxime obtained in Example 2 as the material, tetrahydrofurane as the solvent and a 5% Rh-C catalyst as the catalyst. m-Aminobenzylamine of 99.9% in purity was obtained with an yield of 89.2%.

Sources & evidence

ORD record
ord-31c9fa3ce31f4a0dbbd58d291101bf83
Source dataset
uspto-grants-1988_06
Patent number
US04751328

Reaction notes

Loading…