Water → HCID 13326123, compound

HRID 580650Notes

Reaction equation

HRID 580650 reaction equation
S(C1C=CC(C)=CC=1)([O-])(=O)=O.[Cl:12][C:13]1[CH:35]=[C:34]([Cl:36])[CH:33]=[CH:32][C:14]=1[O:15][CH:16]([O:23][C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][C:25]=1[Cl:31])[CH:17](O)[C:18]([CH3:21])([CH3:20])[CH3:19].O>CS(C)=O>[Cl:12][C:13]1[CH:35]=[C:34]([Cl:36])[CH:33]=[CH:32][C:14]=1[O:15][C:16]([O:23][C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][C:25]=1[Cl:31])=[CH:17][C:18]([CH3:20])([CH3:21])[CH3:19]

Participants

5

Reactant 3

HCID 962WaterHCID 85570p-ToluenesulfonateHCID 13326121HCID 13326121, compound

Product 1

HCID 13326123HCID 13326123, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

An equimolar amount of potassium tert.-butylate is added to 54.6 g (0.1 mole) of the tosylate of 1,1-bis-(2,4-dichlorophenoxy)-3,3-dimethylbutan-2-ol in 200 ml of dry dimethylsulfoxide. The mixture is stirred for 30 minutes at room temperature, after which it is hydrolyzed with water and then extracted twice with the same volume of ethyl acetate, the organic phase is dried and the solvent is distilled off under reduced pressure.

Workup

  1. extractionextracted twice with the same volume of ethyl acetate
  2. customthe organic phase is dried
  3. distillationthe solvent is distilled off under reduced pressure

Sources & evidence

ORD record
ord-dc9355630274448caf5a009d5a477dc8
Source dataset
uspto-grants-1988_06
Patent number
US04754044

Reaction notes

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