Ether hydrochloride → HCID 85707177, compound

Participants

Reaction Steps

To a slurry of 2-(N,N-dimethylaminomethyl)-1-phenyltellurobenzene (1.02 g, 3.0 mmol) in ether (50 mL) in a water bath was added dropwise by syringe a hydrogen chloride/ether solution (3.15 mL, 1.0 M, 3.15 mmol). The thick slurry was diluted with isopropanol (20 mL) then filtered. The white solid was washed with ether, and air dried, to give the product (1.13 g, 95%). 1H NMR (CDCl3) d 2.6 (1H, br s), 8.13 (1H, d, J=7.5), 7.80 (1H, d, J=7.7), 7.52-7.48 (3H, m), 7.26-7.17 (4H, m), 4.44 (2H, d, J=5.8), 2.68 (6H, d, J=4.5). Anal. calc'd for C15H18ClNTe: C, 48.00; H, 4.83; N, 3.73. Found: C, 47.97; H, 4.87; N, 3.65.

Provenance & Evidence