Sodium Iodide → HCID 123825932, compound

HRID 58353Notes

Reaction equation

HRID 58353 reaction equation
Br[C:2]([CH3:27])([CH3:26])[C:3]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][S:12][CH2:13][CH2:14][CH2:15][Si:16]([O:23][CH2:24][CH3:25])([O:20][CH2:21][CH3:22])[O:17][CH2:18][CH3:19])=[O:4].[I-:28].[Na+]>CC(C)=O>[I:28][C:2]([CH3:27])([CH3:26])[C:3]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][S:12][CH2:13][CH2:14][CH2:15][Si:16]([O:23][CH2:24][CH3:25])([O:20][CH2:21][CH3:22])[O:17][CH2:18][CH3:19])=[O:4]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 123835937HCID 123835937, compound

Product 1

HCID 123825932HCID 123825932, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

The 6-(3-(triethoxysilyl)propylthio)hexyl 2-bromo-2-methylpropanate (5 g) obtained through the procedures of Example 1 was mixed with sodium iodide (20 g) and dry acetone (100 mL), and the mixture was allowed to react in a nitrogen atmosphere at 75° C. for 10 hours. After the reaction, extraction was performed to give 6-(3-(triethoxysilyl)propylthio)hexyl 2-iodo-2-methylpropanate of the chemical formula below (compound 6).

Workup

  1. customto react in a nitrogen atmosphere at 75° C. for 10 hours
  2. customAfter the reaction, extraction

Sources & evidence

ORD record
ord-58654fe6280e474cae190bf9ce4486a0
Source dataset
uspto-grants-2016_09
Patent number
US09434794B2

Reaction notes

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