HCID 21311168, compound → HCID 54092533, compound

HRID 583640Notes

Reaction equation

HRID 583640 reaction equation
[CH:1]([C:3](O)([CH2:8][CH2:9][CH2:10][CH3:11])[CH2:4][CH2:5][CH2:6][CH3:7])=[CH2:2]>C1(C)C=CC=CC=1>[CH:1]([C:3]([CH2:8][CH2:9][CH2:10][CH3:11])=[CH:4][CH2:5][CH2:6][CH3:7])=[CH2:2]

Participants

3

Reactant 1

HCID 21311168HCID 21311168, compound

Product 1

HCID 54092533HCID 54092533, compoundYield 56%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A solution of 5.1 grams of 5-vinyl-5-nonanol in 25 ml of toluene containing 38 mg of MTO was refluxed overnight, cooled, washed with aq. potassium carbonate, dried, stripped, and the residue distilled at 25 mm Hg to give 2.55 g (56%) of 5-vinyl-4-nonene as a cis/trans mixture, identified by NMR spectroscopy.

Workup

  1. temperaturecooled
  2. washwashed with aq. potassium carbonate
  3. customdried
  4. distillationthe residue distilled at 25 mm Hg

Sources & evidence

ORD record
ord-ed94fad913c64e4c9f3bfc719d721600
Source dataset
uspto-grants-1999_07
Patent number
US05929298

Reaction notes

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