HRID584309

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=C(OCc1ccc(CBr)cc1COC(=O)c1ccccc1)c1ccccc1

HCID22345618

未命名化合物

结构：CCC(=O)c1ccc(-c2cc(O)ccc2CC)c(C(C)C)c1

HCID22345623

未命名化合物

PRODUCTS

生成物

结构：CCC(=O)c1ccc(-c2cc(OCc3ccc(COC(=O)c4ccccc4)c(COC(=O)c4ccccc4)c3)ccc2CC)c(C(C)C)c1

HCID22345613

未命名化合物

PROCEDURE

实验过程

In a manner similar to that of Example 1(o), by reacting 660 mg (2.2 mmol) of 1-(2′-ethyl-5′-hydroxy-2-isopropylbiphenyl-4-yl)propan-1-one with 1 g (2.3 mmol) of 3,4-bis-(benzoyloxymethyl)benzyl bromide, an oil is obtained, which is used without purification.

WORKUP

后处理

customan oil is obtained
customwhich is used without purification

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-05ef296bdc604a86bd05cce7bc87993b
来源数据集: uspto-grants-2005_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06924400B2
来源说明: uspto-grants-2005_08

反应 SMILES

[CH2:1]([C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][C:4]=1[C:10]1[CH:15]=[CH:14][C:13]([C:16](=[O:19])[CH2:17][CH3:18])=[CH:12][C:11]=1[CH:20]([CH3:22])[CH3:21])[CH3:2].[C:23]([O:31][CH2:32][C:33]1[CH:34]=[C:35]([CH:38]=[CH:39][C:40]=1[CH2:41][O:42][C:43](=[O:50])[C:44]1[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=1)[CH2:36]Br)(=[O:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>>[C:23]([O:31][CH2:32][C:33]1[CH:34]=[C:35]([CH:38]=[CH:39][C:40]=1[CH2:41][O:42][C:43](=[O:50])[C:44]1[CH:45]=[CH:46][CH:47]=[CH:48][CH:49]=1)[CH2:36][O:9][C:6]1[CH:7]=[CH:8][C:3]([CH2:1][CH3:2])=[C:4]([C:10]2[CH:15]=[CH:14][C:13]([C:16](=[O:19])[CH2:17][CH3:18])=[CH:12][C:11]=2[CH:20]([CH3:22])[CH3:21])[CH:5]=1)(=[O:30])[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1