N-formyl-1-aminoundec-10-ene → N-Undecylformamide

HRID 585021Notes

Reaction equation

HRID 585021 reaction equation
[CH:1]([NH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=[CH2:14])=[O:2]>C(O)C.[Pd]>[CH:1]([NH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])=[O:2]

Participants

4

Reactant 1

HCID 12039861N-formyl-1-aminoundec-10-ene

Product 1

HCID 268113N-UndecylformamideYield 100%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

N-formyl-1-aminoundec-10-ene (467 mg) was dissolved in ethanol (2 ml). Pd/C (46 mg) was added and the mixture submitted to hydrogenation at atmospheric pressure during 10 h. The reaction mixture was filtered through a short column of celite and the solvent evaporated under vacuo. This yielded N-formyl-1-aminoundecane (468 mg, yield: 100%) as a white solid

Workup

  1. filtrationThe reaction mixture was filtered through a short column of celite
  2. customthe solvent evaporated under vacuo

Sources & evidence

ORD record
ord-de7c52b32cb441e2b73bdf3b79102a6d
Source dataset
uspto-grants-2005_08
Patent number
US06929685B2

Reaction notes

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