1,3-Cyclohexanedione → HCID 87949497, compound

HRID 585332Notes

Reaction equation

HRID 585332 reaction equation
[Cl:1][C:2]1[C:10]([O:11][CH2:12][C:13](=[N:15][O:16][CH2:17][CH:18]=[CH2:19])[CH3:14])=[C:9]([S:20]([CH2:23][CH3:24])(=[O:22])=[O:21])[CH:8]=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[C:25]1(=O)[CH2:30][CH2:29][CH2:28][C:27](=[O:31])[CH2:26]1.Cl.CN(C)CCCN=C=NCC.CN(C1C=CC=CN=1)C>>[Cl:1][C:2]1[C:10]([O:11][CH2:12][C:13](=[N:15][O:16][CH2:17][CH:18]=[CH2:19])[CH3:14])=[C:9]([S:20]([CH2:23][CH3:24])(=[O:22])=[O:21])[CH:8]=[CH:7][C:3]=1[C:4]([O:6][C:25]1[CH2:30][CH2:29][CH2:28][C:27](=[O:31])[CH:26]=1)=[O:5]

Participants

5

Reactant 4

HCID 104341,3-CyclohexanedioneHCID 218852-DimethylaminopyridineHCID 27239391,3-Propanediamine, N'-(ethylcarbonimidoyl)-N,N-dimethyl-, monohydrochlorideHCID 87990286HCID 87990286, compound

Product 1

HCID 87949497HCID 87949497, compound

Procedure

0.526 g (1.40 mmol) of 2-chloro-3-(2-allyloxyiminopropyloxy)-4-ethanesulfonylbenzoic acid, 0.173 g (1.50 mmol) of cyclohexane-1,3-dione, 0.274 g (1.40 mmol) of N′-(3-dimethylaminopropyl)-N-ethylcarbodiimide hydrochloride and 0.002 g of dimethylaminopyridine were reacted analogously to preparation c).

Sources & evidence

ORD record
ord-e5dcb47ec74c4eb895981d29d8e00ea9
Source dataset
uspto-grants-2005_08
Patent number
US06930208B2

Reaction notes

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