Trifluoroacetic anhydride → HCID 18625207, compound

HRID 589214Notes

Reaction equation

[CH2:1]([Si:9]([CH3:14])([CH3:13])N(C)C)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[F:15][C:16]([F:27])([F:26])[C:17]([O:19]C(=O)C(F)(F)F)=[O:18]>>[F:15][C:16]([F:27])([F:26])[C:17]([O:19][Si:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])([CH3:14])[CH3:13])=[O:18]

Participants

Reactant 2

HCID 9845Trifluoroacetic anhydride2×

HCID 53898681HCID 53898681, compound

Product 1

HCID 18625207HCID 18625207, compound

Procedure

Additionally, for example when mixing octyldimethyl(dimethylamino)silane as the silicon compound B and trifluoroacetic anhydride as the acid B, the trifluoroacetic anhydride is rapidly reacted to form octyldimethylsilyl trifluoroacetate as the acid A.

Sources & evidence

ORD record: ord-e0d33ac473294e3895f5497bed23d644
Source dataset: uspto-grants-2016_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09228120B2

Reaction notes

Loading…