Trifluoromethanesulfonic anhydride → HCID 22506078, compound

HRID 589215Notes

Reaction equation

[CH2:1]([Si:9]([CH3:14])([CH3:13])N(C)C)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[F:15][C:16]([F:29])([F:28])[S:17]([O:20]S(C(F)(F)F)(=O)=O)(=[O:19])=[O:18]>>[F:15][C:16]([F:29])([F:28])[S:17]([O:20][Si:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])([CH3:14])[CH3:13])(=[O:19])=[O:18]

Participants

Reactant 2

HCID 67749Trifluoromethanesulfonic anhydride2×

HCID 53898681HCID 53898681, compound

Product 1

HCID 22506078HCID 22506078, compound

Procedure

Additionally, for example when mixing octyldimethyl(dimethylamino)silane as the silicon compound B and trifluoromethanesulfonic anhydride as the acid B, the trifluoromethanesulfonic anhydride is rapidly reacted to form octyldimethylsilyl trifluoromethanesulfonate as the acid A.

Sources & evidence

ORD record: ord-f3f84c4464534b1091a329016049614f
Source dataset: uspto-grants-2016_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09228120B2

Reaction notes

Loading…