Styrene → trans-Stilbene

HRID 589531Notes

Reaction equation

HRID 589531 reaction equation
I[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:8]=[CH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>>[C:2]1(/[CH:8]=[CH:9]/[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 7501StyreneHCID 11575Iodobenzene

Product 1

HCID 638088trans-Stilbene

Procedure

Iodobenzene (32 μL, 0.25 mmol) and styrene (43 μL, 0.375 mmol) were coupled using the procedure described above to give 81% conversion to (E)-stilbene by GC analysis.

Sources & evidence

ORD record
ord-b42a0c227f9a4af8b1e31e04310cb500
Source dataset
uspto-grants-2016_01
Patent number
US09233366B2

Reaction notes

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