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HRID589987

反应详情

EQUATION

反应方程式

HRID 589987 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)OC(=O)NCCC(=O)C1C(=O)OC(C)(C)OC1=O
HCID68556020

tert-Butyl [3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-oxopropyl]carbamate

C14H21NO7

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)N1CCC(=O)CC1=O
HCID23730999

tert-Butyl 2,4-dioxopiperidine-1-carboxylate

C10H15NO4

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOC(C)=O
溶剂HCID8857

Ethyl acetate

C4H8O2

PROCEDURE

实验过程

A solution of tert-butyl[3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-oxopropyl]carbamate (8.3 g, 26.3 mmol) in EtOAc (130 mL) was heated at reflux for 4 h. The solution was concentrated to afford the title compound which was used without further purification. LRMS (ESI) m/z 214.2 [(M+H)+; calcd for C10H15NO4: 214].

WORKUP

后处理

  1. temperatureat reflux for 4 h
  2. concentrationThe solution was concentrated