Methyl 6-heptenoate → Methyl 6-((tert-butylsulfinyl)imino)hexanoate

HRID 594326Notes

Reaction equation

HRID 594326 reaction equation
C(OC)(=O)CCCCC=C.[C:11]([S:15]([N:17]=[CH:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O:25][CH2:26]C)=[O:24])=[O:16])([CH3:14])([CH3:13])[CH3:12]>>[C:11]([S:15]([N:17]=[CH:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O:25][CH3:26])=[O:24])=[O:16])([CH3:14])([CH3:13])[CH3:12]

Participants

3

Reactant 2

HCID 554040Methyl 6-heptenoateHCID 86695621Ethyl 6-((tert-butylsulfinyl)imino)hexanoate

Product 1

HCID 86695622Methyl 6-((tert-butylsulfinyl)imino)hexanoate

Procedure

Methyl 6-((tert-butylsulfinyl)imino)hexanoate was prepared from methyl hept-6-enoate according to the procedure described for ethyl 6-((tert-butylsulfinyl)imino)hexanoate. Purification by FC (DCM/MeOH=25/1) afforded methyl 6-((tert-butylsulfinyl)imino)hexanoate as a yellow oil. LC-MS (conditions D): tR=0.87 min.; [M+H]+: 248.17 g/mol.

Workup

  1. customPurification by FC (DCM/MeOH=25/1)

Sources & evidence

ORD record
ord-4dda4f7234c94837afbc32ce19a2fe70
Source dataset
uspto-grants-2016_01
Patent number
US09242970B2

Reaction notes

Loading…