HRID595332

反应详情

EQUATION

反应方程式

HRID 595332 的结构方程式

CONDITIONS

反应条件

温度
120 °C

PROCEDURE

实验过程

A solution of 4-[(benzyloxy)methyl]-5-{[4-(3-{[4-(difluoromethyl)pyrimidin-2-yl]amino}-5-methylphenyl)-1H-pyrazol-1-yl]methyl}-1,3-oxazolidin-2-one (100 mg, 0.199 mmol) in TFA (1.0 mL) was stirred and heated at 120° C. in a microwave reactor for 40 minutes. The reaction mixture was concentrated under reduced pressure to afford (5-{[4-(3-{[4-(difluoromethyl)pyrimidin-2-yl]amino}-5-methylphenyl)-1H-pyrazol-1-yl]methyl}-2-oxo-1,3-oxazolidin-4-yl)methyl trifluoroacetate, which was used in the next step without further purification. MS ESI calc'd. for C22H20F5N6O4 [M+H]+ 527. found 527.

WORKUP

后处理

  1. concentrationThe reaction mixture was concentrated under reduced pressure