HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyldithiocarbamic acid, dimethylamine → 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyldithiocarbamic acid, dimethylamine | HCID 11728 | — |
| Reactant | 3,4-Dimethoxy-beta-nitrostyrene | HCID 222093 | — |
| Solvent | Carbon Disulfide | HCID 6348 | — |
| Product | 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate | HCID 21324596 | — |
Reaction Steps
As in Example 17, reaction of 3,4-dimethoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-dimethoxy-α-(nitromethyl)-benzyl dimethyldithiocarbamate melting at 108° C.-110° C. after recrystallization without heating from acetone-methanol solution.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04011230 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-3988e83e65054981a44da5047bbc4b0f |
| Source note | uspto-grants-1977_03 |