Dimethyldithiocarbamic acid, dimethylamine → p-Isopropyl-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 596506Notes

Reaction equation

HRID 596506 reaction equation
[CH:1]([C:4]1[CH:14]=[CH:13][C:7]([CH:8]=[CH:9][N+:10]([O-:12])=[O:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2].[CH3:15][N:16]([CH3:20])[C:17](=[S:19])[S-:18].C[NH2+]C>C(=S)=S>[CH3:15][N:16]([CH3:20])[C:17](=[S:18])[S:19][CH:8]([CH2:9][N+:10]([O-:12])=[O:11])[C:7]1[CH:13]=[CH:14][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 2737867p-Isopropyl-beta-nitrostyrene

Product 1

HCID 21324607p-Isopropyl-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of p-isopropyl-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-isopropyl-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 119° C.-120° C. after recrystallization without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-0f750e2804cc4f2cac0bf7ad3717a307
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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