Dimethyldithiocarbamic acid, dimethylamine → p-Methoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 596509Notes

Reaction equation

HRID 596509 reaction equation
[CH3:1][O:2][C:3]1[CH:13]=[CH:12][C:6]([CH:7]=[CH:8][N+:9]([O-:11])=[O:10])=[CH:5][CH:4]=1.[CH3:14][N:15]([CH3:19])[C:16](=[S:18])[S-:17].C[NH2+]C>C(=S)=S>[CH3:14][N:15]([CH3:19])[C:16](=[S:17])[S:18][CH:7]([CH2:8][N+:9]([O-:11])=[O:10])[C:6]1[CH:5]=[CH:4][C:3]([O:2][CH3:1])=[CH:13][CH:12]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 2298434-Methoxy-beta-nitrostyrene

Product 1

HCID 21324614p-Methoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of p-methoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-methoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 86° C.-89° C. when recrystallized without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-ea8216732bb84738b54a214081e7a237
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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