Sodium hydride → 3-Methoxybenzaldehyde

HRID 596614Notes

Reaction equation

[H-].[Na+].[I-].C[S+](C)C.[CH3:8][O:9][C:10]1[CH:11]=[C:12]([CH:16]=[CH:17][CH:18]=1)[CH:13]1[O:15]C1>>[CH3:8][O:9][C:10]1[CH:11]=[C:12]([CH:16]=[CH:17][CH:18]=1)[CH:13]=[O:15]

Participants

Reactant 3

HCID 24758Sodium hydride

HCID 75127Trimethylsulfonium iodide

HCID 979032-(3-Methoxyphenyl)oxirane

Product 1

HCID 115693-Methoxybenzaldehyde

Procedure

Following the procedure of Example 7 and employing 2.42 g. of sodium hydride, 9.46 g. of trimethylsulfonium iodide and 6.33 g. (0.046 mol) of m-methoxybenzaldehyde there is obtained m-methoxystyrene oxide.

Sources & evidence

ORD record: ord-9117baebc4c948938188a6ee1e1ed5a4
Source dataset: uspto-grants-1977_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04011319

Reaction notes

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