Dimethylamine → HCID 3927375, compound

HRID 596661Notes

Reaction equation

HRID 596661 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:15]=[CH:16][CH:17]=1)[NH:7][C:8](=[O:14])[C:9]([O:11]CC)=O)([O-:3])=[O:2].[CH3:18][NH:19][CH3:20]>C(Cl)Cl>[CH3:18][N:19]([CH3:20])[C:9]([C:8]([NH:7][C:6]1[CH:15]=[CH:16][CH:17]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=1)=[O:14])=[O:11]

Participants

4

Reactant 2

HCID 674DimethylamineHCID 243437ST51021144

Product 1

HCID 3927375HCID 3927375, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A solution of 11.91 gm. (0.05 mole) of ethyl 3-nitro-oxanilate in 500 ml. of methylene chloride is cooled to 5° in an ice bath. There is added slowly, 25 ml. of dimethylamine and the mixture stirred for two hours in an ice-bath. The ice-bath is removed and the mixture allowed to stand at room temperature overnight.

Workup

  1. additionThere is added slowly
  2. customThe ice-bath is removed

Sources & evidence

ORD record
ord-72dc7ace2cc94b2cb92412f4561e3f5b
Source dataset
uspto-grants-1977_03
Patent number
US04011337

Reaction notes

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