Ammonia → HCID 70638421, compound

HRID 597141Notes

Reaction equation

HRID 597141 reaction equation
[NH3:1].[C:2]1([C:8](=[CH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH2:9][Cl:10])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>C1C=CC=CC=1>[ClH:10].[C:2]1([C:8](=[CH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH2:9][NH2:1])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 222AmmoniaHCID 54379748Benzene, 1,1′-[1-(chloromethyl)-1,2-ethenediyl]bis-

Product 1

HCID 70638421HCID 70638421, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

Ammonia under pressure is added to a solution of 4 parts of 2,3-diphenylallyl chloride in 44 parts of benzene at 70° for 24 hours. After that time, the solid is separated by filtration and the benzene solution is reduced to an oil under reduced pressure. The oil is dissolved in isopropanolic hydrochloric acid and then diluted with ethyl ether to precipitate a solid. The solid is collected by filtration and dried to yield pure 2,3-diphenylallylamine hydrochloride, displaying nuclear magnetic resonance maxima at about 240, 241, 413, 426 and 442 Hertz and represented by the following structural formula ##STR5##

Workup

  1. customAfter that time, the solid is separated by filtration
  2. dissolutionThe oil is dissolved in isopropanolic hydrochloric acid
  3. additiondiluted with ethyl ether
  4. customto precipitate a solid
  5. filtrationThe solid is collected by filtration
  6. customdried

Sources & evidence

ORD record
ord-bcebaa8cd18046c98191ec294eab7fc8
Source dataset
uspto-grants-1977_03
Patent number
US04013643

Reaction notes

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