Allylamine → HCID 86733611, compound

HRID 597510Notes

Reaction equation

HRID 597510 reaction equation
[N+:1]([C:4]1[C:9]([CH:10]=O)=[CH:8][C:7]([O:12][CH3:13])=[C:6]([O:14][CH3:15])[CH:5]=1)([O-:3])=[O:2].[CH2:16]([NH2:19])[CH:17]=[CH2:18]>C(O)C>[N+:1]([C:4]1[C:9]([CH:10]=[C:18]=[CH:17][CH2:16][NH2:19])=[CH:8][C:7]([O:12][CH3:13])=[C:6]([O:14][CH3:15])[CH:5]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 7853AllylamineHCID 885056-Nitroveratraldehyde

Product 1

HCID 86733611HCID 86733611, compoundYield 99.9%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

A suspension of 6-nitroveratraldehyde (84 g, 0.4 mole) and ethanol (1200 ml) was refluxed with a solution of allylamine (21 g, 0.44 mole) and ethanol (100 ml) for 1.5 hrs. The resulting dark solution was concentrated to dryness in vacuo leaving 100 g of a dark oil which solidified.

Workup

  1. concentrationThe resulting dark solution was concentrated to dryness in vacuo

Sources & evidence

ORD record
ord-8ba02b623eae407aaf4ba96d68b98bb8
Source dataset
uspto-grants-1977_03
Patent number
US04014886

Reaction notes

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