HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → HCID 14037812, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | HCID 21258231 | HCID 21258231 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 14037812 | HCID 14037812 | — |
Reaction Steps
The benzo[c]phenanthridine methosulfate (I, R5 is methyl, X is methosulfate) is also the intermediate from which 5,6-dihydrobenzo[c]phenanthridine (II) is obtained by reaction with aqueous ammonia. When the reaction between a benzo[c]phenanthridinium methosulfate and aqueous ammonia is followed by a reaction with methanol or any other alcohol, 5,6-dihydro-6-alkoxybenzo[c]phenanthridines are obtained (II, R5 is methyl, R6 is alkoxy).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04014885 |
| Source dataset | uspto-grants-1977_03 |
| ORD ID | ord-f8cb469b48b1447a8b7c66e93765db7d |
| Source note | uspto-grants-1977_03 |