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HRID597559

反应详情

EQUATION

反应方程式

HRID 597559 的结构方程式

REACTANTS

反应物

1
结构：[N-]=[N+]=Nc1c(-c2ccccc2)c2ccccc2[nH]c1=O
HCID21445440

3-Azido-4-phenyl-2(1H)-quinolinone

C15H10N4O

PRODUCTS

生成物

1
结构：O=c1[nH]c2ccccc2c2c1[nH]c1ccccc12
HCID21445410

5,7-Dihydro-6H-indolo[2,3-c]quinolin-6-one

C15H10N2O

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A suspension of 114 g. of 3-azido-4-phenylcarbostyril in 2 l. of toluene was heated to reflux until nitrogen evolution ceased (5 hours). On cooling, 7H-indolo[2,3-c]quinolin-6(5H)-one crystallized; 84.7 g. (84 percent), having a melting point of 314°-316° .

WORKUP

后处理

  1. additionA suspension of 114 g
  2. temperatureto reflux until nitrogen evolution
  3. custom(5 hours)
  4. temperatureOn cooling
  5. custom7H-indolo[2,3-c]quinolin-6(5H)-one crystallized