HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Cyclooctanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Cyclooctanol | HCID 12766 | — |
| Catalyst | Platinum | HCID 23939 | — |
| Solvent | Water | HCID 962 | — |
| Product | Cyclooctanone | HCID 10403 | 87% |
Reaction Steps
In an ambient pressure oxygen atmosphere, 26.4 mg of cyclooctanol and 34.1 mg of the platinum catalyst obtained in Example 1 were agitated for twelve hours at 60° C. in 2 ml of water. The reaction mixture was subsequently extracted using ethyl acetate, and the organic layer was dried using magnesium sulfate, filtered and concentrated to obtain 22.6 mg (87% yield) of cyclooctanone. The reaction equation and the analytical results of the product are shown below.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07897817B2 |
| Source dataset | uspto-grants-2011_03 |
| ORD ID | ord-f36aa0aa904140b9bffe31bce7c19e4d |
| Source note | uspto-grants-2011_03 |