Palladium Chloride → HCID 22617121, compound

HRID 600170Notes

Reaction equation

HRID 600170 reaction equation
[Pd:1]([Cl:3])[Cl:2].[Cl-].[Li+].[C:6]12[CH2:12][C:9]([CH2:10][CH2:11]1)=[CH:8][CH:7]=2>CO>[Cl:2][Pd:1][Cl:3].[C:6]12[CH2:12][C:9]([CH2:10][CH2:11]1)=[CH:8][CH:7]=2

Participants

5

Reactant 3

HCID 24290Palladium ChlorideHCID 433294Lithium ChlorideHCID 18006658Norborna-diene

Product 1

HCID 22617121HCID 22617121, compoundYield 79%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Palladium chloride (3.00 g; manufactured by Wako Pure Chemical Industry), 2.10 g of lithium chloride (manufactured by Wako Pure Chemical Industry) and 40 mL of methanol were charged in a flask made of glass where the inner air was substituted with highly pure argon and were stirred for 4 hours. Norbornadiene (2.1 g; manufactured by Aldrich) was added to the resulting homogeneous solution and the mixture was stirred for 12 hours. The resulting yellow solid was sucked to give 3.6 g of norbornadiene dichloropalladium.

Workup

  1. stirringthe mixture was stirred for 12 hours

Sources & evidence

ORD record
ord-d10d80078eea4658a9c7058419dee675
Source dataset
uspto-grants-2011_03
Patent number
US07902109B2

Reaction notes

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