Sodium Methoxide → HCID 86634829, compound

HRID 600171Notes

Reaction equation

HRID 600171 reaction equation
[Cl:1][Pd:2][Cl:3].[C:4]12[CH2:10][C:7]([CH2:8][CH2:9]1)=[CH:6][CH:5]=2.[CH3:11][O-:12].[Na+]>CO>[Pd:2]([Cl:3])[Cl:1].[CH3:11][O:12][C:4]12[CH2:10][CH:7]([CH2:8][CH2:9]1)[CH:6]=[CH:5]2

Participants

4

Reactant 2

HCID 10942334Sodium MethoxideHCID 22617121HCID 22617121, compound

Product 1

HCID 86634829HCID 86634829, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The above-prepared norbornadiene dichloropalladium (1.40 g) was added to 20 mL of methanol in a flask made of glass where inner air was substituted with highly pure argon and then the inner temperature was made −40° C. using a dry ice bath. Into this was dropped 1.5 mL of a 28% methanolic solution of sodium methoxide (manufactured by Wako Pure Chemical Industry). The mixture was made to react for 1 hour and returned to room temperature. The resulting yellow solid was sucked and washed with methanol to give 1.22 g of methoxynorbornene palladium chloride dimer.

Workup

  1. customwas made −40° C.
  2. customto react for 1 hour
  3. customreturned to room temperature
  4. washwashed with methanol

Sources & evidence

ORD record
ord-6f02379f7f25402e8c0c3866a01acda2
Source dataset
uspto-grants-2011_03
Patent number
US07902109B2

Reaction notes

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