Sodium borohydride → 2,4-Bis(tert-butyl)-6-[[(2,6-dichlorophenyl)amino]methyl]-phenol

Participants

Role	Name	HCID	Charge
Reactant	Sodium borohydride	HCID 4311764	—
Reactant	2,4-Bis(tert-butyl)-6-[[(2,6-dibromophenyl)amino]methyl]phenol	HCID 86627667	—
Reactant	2,4-Bis(tert-butyl)-6-[[(2,6-dichlorophenyl)imino]methyl]phenol	HCID 136346709	—
Product	2,4-Bis(tert-butyl)-6-[[(2,6-dichlorophenyl)amino]methyl]-phenol	HCID 86627666	—

Reaction Steps

Using an analogous procedure to the synthesis of 2,4-bis(tert-butyl)-6-[[(2,6-dibromophenyl)amino]methyl]phenol described above, NaBH4 (0.8 g) was added to a solution of 2,4-bis(tert-butyl)-6-[[(2,6-dichlorophenyl)imino]methyl]phenol (0.91 g, 2.41 mmol). The product was purified from hot hexane and isolated as colourless crystals. Yield 0.61 g, 67%.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US07902308B2
Source dataset	uspto-grants-2011_03
ORD ID	ord-ee8661360f144b058500a09e18e60a14
Source note	uspto-grants-2011_03