Ammonia → HCID 85967345, compound

HRID 601147Notes

Reaction equation

HRID 601147 reaction equation
[NH:1]1[C:6]2N=CC=[CH:10][C:5]=2[C:4](=[O:11])[O:3][C:2]1=[O:12].Br[CH2:14][CH2:15][CH:16]([CH3:18])[CH3:17].[CH2:19](Br)CCC.N>>[CH3:19][C:6]1[N:1]([CH2:14][CH2:15][CH:16]([CH3:18])[CH3:17])[C:2](=[O:12])[O:3][C:4](=[O:11])[C:5]=1[CH3:10]

Participants

5

Reactant 4

HCID 222AmmoniaHCID 78911-Bromo-3-methylbutaneHCID 8002Butyl bromideHCID 109865823-Azaisatoic anhydride

Product 1

HCID 85967345HCID 85967345, compound

Procedure

The title compound was prepared according to the procedure of Example 1B substituting the product of Example 123A for the product of Example 1A and substituting 1-bromo-3-methyl butane for n-butyl bromide (0.224 g, 60%). MS (DCI/NH3) m/z 255 (M+NH4)+; 1H NMR (300 MHz, DMSO-d6) δ 0.92 (d, J=6.62 Hz, 6 H) 1.46 (m, 2 H) 1.59 (dt, J=13.14, 6.48 Hz, 1 H) 1.85 (s, 3 H) 2.26 (s, 3 H) 3.77 (m, 2 H).

Sources & evidence

ORD record
ord-04fdeda3ea624e12b00a78eb94ba6145
Source dataset
uspto-grants-2011_03
Patent number
US07902203B2

Reaction notes

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