HuagongsheHuagongshe Chemistry Print Report · For research reference only
cis-Crotyl Bromide → HCID 59180186, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | cis-Crotyl Bromide | HCID 5354843 | — |
| Reactant | 3-TETRAHYDROPYRANYLOXY-1-TRIMETHYLSILYL-1-PROPYNE | HCID 10703781 | — |
| Product | HCID 59180186 | HCID 59180186 | — |
Reaction Steps
Reaction of trimethyl(3-(tetrahydro-2H-pyran-2-yloxy)prop-1-ynyl)silane (0.157 g, 0.74 mmol) and (Z)-1-bromobut-2-ene (0.12 g, 0.89 mmol) according to General Procedure 11.A provided (Z)-trimethyl(3-(tetrahydro-2H-pyran-2-yloxy)hept-5-en-1-ynyl)silane. The (Z)-1-bromobut-2-ene starting material was synthesized in two steps according to General Procedures 11.F and 11.G.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07902252B2 |
| Source dataset | uspto-grants-2011_03 |
| ORD ID | ord-eedfeddc061b47158b280c2acc2c6cf7 |
| Source note | uspto-grants-2011_03 |