Ammonium Chloride → HCID 66808634, compound

HRID 605199Notes

Reaction equation

HRID 605199 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]([CH:8]([O:10][C:11]2[CH:16]=[CH:15][C:14]([S:17][C:18]3[CH:23]=[CH:22][C:21]([OH:24])=[CH:20][CH:19]=3)=[C:13]([N+:25]([O-])=O)[CH:12]=2)[CH3:9])[CH:5]=[CH:6][CH:7]=1.[NH4+].[Cl-]>[Fe]>[NH2:25][C:13]1[CH:12]=[C:11]([O:10][CH:8]([C:4]2[CH:5]=[CH:6][CH:7]=[C:2]([Br:1])[CH:3]=2)[CH3:9])[CH:16]=[CH:15][C:14]=1[S:17][C:18]1[CH:19]=[CH:20][C:21]([OH:24])=[CH:22][CH:23]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 66808316HCID 66808316, compound

Product 1

HCID 66808634HCID 66808634, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 168c (5.4 g, 12.2 mmol) was reacted with Fe and NH4Cl as described in Example 9E to give the title compound (3.6 g, 76%).

Sources & evidence

ORD record
ord-0f4a8cde4ecc409a92188386b2e6f336
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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