Ammonium Chloride → HCID 67040228, compound

HRID 605203Notes

Reaction equation

HRID 605203 reaction equation
[C:1]([O:5][C:6](=[O:37])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([C:21](=[O:33])[NH:22][C:23]3[CH:28]=[CH:27][C:26]([C:29]([F:32])([F:31])[F:30])=[CH:25][CH:24]=3)=[CH:17][C:16]=2[N+:34]([O-])=O)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[NH4+].[Cl-]>[Fe]>[C:1]([O:5][C:6](=[O:37])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([C:21](=[O:33])[NH:22][C:23]3[CH:28]=[CH:27][C:26]([C:29]([F:31])([F:30])[F:32])=[CH:25][CH:24]=3)=[CH:17][C:16]=2[NH2:34])=[CH:10][CH:9]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67040570HCID 67040570, compound

Product 1

HCID 67040228HCID 67040228, compoundYield 90%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 172c was reacted with Fe and NH4Cl following the procedure of Example 9E to give the title compound (204 mg, 90%).

Sources & evidence

ORD record
ord-d538d0fd90d94fcd9cf738bc057a6dfd
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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