Ammonium Chloride → HCID 67040285, compound

HRID 605246Notes

Reaction equation

HRID 605246 reaction equation
[Cl:1][C:2]([Cl:35])([Cl:34])[CH2:3][O:4][C:5](=[O:33])[NH:6][C:7]1[CH:12]=[CH:11][C:10]([S:13][C:14]2[CH:19]=[CH:18][C:17]([NH:20][C:21](=[O:29])[C:22]3[CH:27]=[CH:26][C:25]([F:28])=[CH:24][CH:23]=3)=[CH:16][C:15]=2[N+:30]([O-])=O)=[CH:9][CH:8]=1.[NH4+].[Cl-]>[Fe]>[Cl:35][C:2]([Cl:1])([Cl:34])[CH2:3][O:4][C:5](=[O:33])[NH:6][C:7]1[CH:12]=[CH:11][C:10]([S:13][C:14]2[CH:19]=[CH:18][C:17]([NH:20][C:21](=[O:29])[C:22]3[CH:27]=[CH:26][C:25]([F:28])=[CH:24][CH:23]=3)=[CH:16][C:15]=2[NH2:30])=[CH:9][CH:8]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67040947HCID 67040947, compound

Product 1

HCID 67040285HCID 67040285, compoundYield 60%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 238d (0.88 g, 1.6 mmol) was reacted with Fe and NH4Cl as described for Example 9E to give the desired product (0.50 g, 60%).

Sources & evidence

ORD record
ord-7952e03b19f64cc4aafd52df8904c80c
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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