Ammonium Chloride → HCID 67040605, compound

HRID 605250Notes

Reaction equation

HRID 605250 reaction equation
[Cl:1][CH:2]([Cl:36])[CH2:3][O:4][C:5](=[O:35])[NH:6][C:7]1[CH:12]=[CH:11][C:10]([S:13][C:14]2[CH:19]=[CH:18][C:17]([NH:20][C:21](=[O:31])[C:22]3[CH:27]=[CH:26][CH:25]=[C:24]([N:28]([CH3:30])[CH3:29])[CH:23]=3)=[CH:16][C:15]=2[N+:32]([O-])=O)=[CH:9][CH:8]=1.[NH4+].[Cl-]>[Fe]>[Cl:36][CH:2]([Cl:1])[CH2:3][O:4][C:5](=[O:35])[NH:6][C:7]1[CH:12]=[CH:11][C:10]([S:13][C:14]2[CH:19]=[CH:18][C:17]([NH:20][C:21](=[O:31])[C:22]3[CH:27]=[CH:26][CH:25]=[C:24]([N:28]([CH3:30])[CH3:29])[CH:23]=3)=[CH:16][C:15]=2[NH2:32])=[CH:9][CH:8]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67040418HCID 67040418, compound

Product 1

HCID 67040605HCID 67040605, compoundYield 58.8%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 239d (2.0 g, 3.6 mmol) was reacted with Fe and NH4Cl as described for Example 9E to give the desired product (1.1 g, 58%).

Sources & evidence

ORD record
ord-f2ae46cffe5a46bc9613de336982bf15
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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