Ammonium Chloride → HCID 67040412, compound

HRID 605261Notes

Reaction equation

HRID 605261 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([NH:18][C:19](=[O:30])[C:20]2[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([F:29])([F:28])[F:27])[CH:21]=2)[CH:7]=[CH:8][C:9]=1[S:10][C:11]1[CH:16]=[CH:15][C:14]([CH3:17])=[CH:13][CH:12]=1)([O-])=O.[NH4+].[Cl-]>[Fe]>[NH2:1][C:4]1[CH:5]=[C:6]([NH:18][C:19](=[O:30])[C:20]2[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([F:29])([F:27])[F:28])[CH:21]=2)[CH:7]=[CH:8][C:9]=1[S:10][C:11]1[CH:12]=[CH:13][C:14]([CH3:17])=[CH:15][CH:16]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67040447HCID 67040447, compound

Product 1

HCID 67040412HCID 67040412, compoundYield 73%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 243a was reduced with Fe and NH4Cl following the procedure from Example 9E to give the title compound (420 mg, 73%).

Sources & evidence

ORD record
ord-ca2e8f841e22498ba50256c5066e0e6b
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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