Ammonium Chloride → HCID 67040537, compound

HRID 605269Notes

Reaction equation

HRID 605269 reaction equation
[C:1]([O:5][C:6](=[O:35])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22](=[O:31])[C:23]3[CH:28]=[C:27]([Cl:29])[CH:26]=[C:25]([Cl:30])[CH:24]=3)=[CH:17][C:16]=2[N+:32]([O-])=O)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[NH4+].[Cl-]>[Fe]>[C:1]([O:5][C:6](=[O:35])[NH:7][C:8]1[CH:9]=[CH:10][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22](=[O:31])[C:23]3[CH:28]=[C:27]([Cl:29])[CH:26]=[C:25]([Cl:30])[CH:24]=3)=[CH:17][C:16]=2[NH2:32])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67041082HCID 67041082, compound

Product 1

HCID 67040537HCID 67040537, compoundYield 58.8%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 254b (1.1 g, 2.1 mmol) was reacted with Fe and NH4Cl as described for Example 9E to give the desired product (0.6 g, 58.8%).

Sources & evidence

ORD record
ord-964ba13c5f1243649bf081d4803c2a33
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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