Ammonium Chloride → HCID 67040936, compound

HRID 605274Notes

Reaction equation

HRID 605274 reaction equation
[C:1]([O:5][C:6](=[O:32])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22]([C:24]3[S:25][CH:26]=[CH:27][CH:28]=3)=[O:23])=[CH:17][C:16]=2[N+:29]([O-])=O)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[NH4+].[Cl-]>[Fe]>[C:1]([O:5][C:6](=[O:32])[NH:7][C:8]1[CH:9]=[CH:10][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22]([C:24]3[S:25][CH:26]=[CH:27][CH:28]=3)=[O:23])=[CH:17][C:16]=2[NH2:29])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67040738HCID 67040738, compound

Product 1

HCID 67040936HCID 67040936, compoundYield 65%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 256b was reduced with Fe and NH4Cl using the conditions of Example 9E to provide the title compound (1.25 g, 65%).

Sources & evidence

ORD record
ord-b4475555d93b46c6a8d0fc351e103fe4
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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