Ammonium Chloride → HCID 67041071, compound

HRID 605277Notes

Reaction equation

HRID 605277 reaction equation
[C:1]([O:5][C:6](=[O:33])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22]([C:24]3[S:25][C:26]([Br:29])=[CH:27][CH:28]=3)=[O:23])=[CH:17][C:16]=2[N+:30]([O-])=O)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[NH4+].[Cl-]>[Fe]>[C:1]([O:5][C:6](=[O:33])[NH:7][C:8]1[CH:9]=[CH:10][C:11]([O:14][C:15]2[CH:20]=[CH:19][C:18]([NH:21][C:22]([C:24]3[S:25][C:26]([Br:29])=[CH:27][CH:28]=3)=[O:23])=[CH:17][C:16]=2[NH2:30])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 67041089HCID 67041089, compound

Product 1

HCID 67041071HCID 67041071, compoundYield 50%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 257a was reduced with Fe and NH4Cl following the procedure from Example 9E to provide the title compound (922 mg, 50%).

Sources & evidence

ORD record
ord-fdbe8a3009e24525a9239bb225aec2b3
Source dataset
uspto-grants-2011_03
Patent number
US07910595B2

Reaction notes

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