Hydroquinone → 1-(4-Methoxy-phenoxy)-4-methyl-2-nitro-benzene

HRID 607224Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1.F[C:11]1[CH:16]=[CH:15][C:14]([CH3:17])=[CH:13][C:12]=1[N+:18]([O-:20])=[O:19].C1(C=CC(O)=CC=1)O>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([O:9][C:11]2[CH:16]=[CH:15][C:14]([CH3:17])=[CH:13][C:12]=2[N+:18]([O-:20])=[O:19])=[CH:5][CH:4]=1

Participants

Reactant 3

HCID 785Hydroquinone

HCID 90154-Methoxyphenol

HCID 1362874-Fluoro-3-nitrotoluene

Product 1

HCID 104914931-(4-Methoxy-phenoxy)-4-methyl-2-nitro-benzene

Procedure

4-Methoxy-phenol was reacted with 1-fluoro-4-methyl-2-nitrobenzene according to the procedure from Example 122a substituting 4-methoxy-phenol for hydroquinone to provide the title compound.

Sources & evidence

ORD record: ord-c8306aea5fca4d21914b592a5460a8ab
Source dataset: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07915411B2

Reaction notes

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