HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methoxybenzenethiol → 1-(4-Methoxy-phenylsulfanyl)-4-methyl-2-nitro-benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methoxybenzenethiol | HCID 12765 | — |
| Reactant | 4-Methyl-2-nitrophenyl trifluoromethanesulfonate | HCID 71346889 | — |
| Product | 1-(4-Methoxy-phenylsulfanyl)-4-methyl-2-nitro-benzene | HCID 60204792 | — |
Reaction Steps
The product from Example 6a (5.0 g, 175 mmol) was reacted with 4-methoxy-benzenethiol (2.45 g, 175 mmol) for 18 h following the procedure from Example 6b giving 1-(4-methoxy-phenylsulfanyl)-4-methyl-2-nitro-benzen, which was reduced with SnCl2 following the procedure from Example 5I giving 2-(4-Methoxy-phenylsulfanyl)-5-methyl-phenylamine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07915411B2 |
| Source dataset | uspto-grants-2011_03 |
| ORD ID | ord-d800b32fd35f42bd9c62684e051e6eea |
| Source note | uspto-grants-2011_03 |