Hydroquinone → 4-(2-Amino-4-benzyloxy-phenoxy)-phenol

HRID 607305Notes

Reaction equation

HRID 607305 reaction equation
[CH2:1]([O:8][C:9]1[CH:14]=[CH:13][C:12](Cl)=[C:11]([N+:16]([O-])=O)[CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:19]1([CH:26]=[CH:25][C:23]([OH:24])=[CH:22][CH:21]=1)[OH:20]>>[NH2:16][C:11]1[CH:10]=[C:9]([O:8][CH2:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH:14]=[CH:13][C:12]=1[O:20][C:19]1[CH:26]=[CH:25][C:23]([OH:24])=[CH:22][CH:21]=1

Participants

3

Reactant 2

HCID 785HydroquinoneHCID 110436225-Benzyloxy-2-chloro-nitrobenzene

Product 1

HCID 668085774-(2-Amino-4-benzyloxy-phenoxy)-phenol

Procedure

4-Benzyloxy-1-chloro-2-nitro-benzene (from Example 27A) was reacted with hydroquinone according to the procedure from Example 39A and reduced according to the procedure from Example 39B to provide the title product.

Sources & evidence

ORD record
ord-0824d3b5fa954fb8b40a76af25db3784
Source dataset
uspto-grants-2011_03
Patent number
US07915411B2

Reaction notes

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