Ammonium Chloride → HCID 66808634, compound

HRID 607309Notes

Reaction equation

HRID 607309 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]([CH:8]([O:10][C:11]2[CH:16]=[CH:15][C:14]([S:17][C:18]3[CH:23]=[CH:22][C:21]([OH:24])=[CH:20][CH:19]=3)=[C:13]([N+:25]([O-])=O)[CH:12]=2)[CH3:9])[CH:5]=[CH:6][CH:7]=1.[NH4+].[Cl-]>[Fe]>[NH2:25][C:13]1[CH:12]=[C:11]([O:10][CH:8]([C:4]2[CH:5]=[CH:6][CH:7]=[C:2]([Br:1])[CH:3]=2)[CH3:9])[CH:16]=[CH:15][C:14]=1[S:17][C:18]1[CH:19]=[CH:20][C:21]([OH:24])=[CH:22][CH:23]=1

Participants

4

Reactant 2

HCID 25517Ammonium ChlorideHCID 66808316HCID 66808316, compound

Product 1

HCID 66808634HCID 66808634, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

The product from Example 228c (5.4 g, 12.2 mmol) was reacted with Fe and NH4Cl as described in Example 10E to give the title compound (3.6 g, 76%).

Sources & evidence

ORD record
ord-c201175954ac437eb2c1c7bc124b0c1c
Source dataset
uspto-grants-2011_03
Patent number
US07915411B2

Reaction notes

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