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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 610737Generated: October 26, 2026

Formic Acid → (E)-but-2-enedioic acid;copper

https://huagongshe.com/reaction/610737

Reaction equation

Participants

RoleNameHCIDCharge
ReactantFormic AcidHCID 284—
ReactantFumaric AcidHCID 444972—
ReactantFormic acid, copper saltHCID 44152240—
SolventMethanolHCID 887—
Product(E)-but-2-enedioic acid;copperHCID 9047154573.8%

Reaction Steps

1.2 g of fumaric acid was dissolved under heating in a mixture solvent of 100 cm3 of methanol and 12 cm3 of formic acid. After this solution was cooled to the normal temperature, into this solution, a further solution in which 3.38 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped and then this was kept still for one day. Thereafter, the precipitation product was suction-filtered and dried for 120° C./4 hours, whereby 1.37 g of fumaric acid copper was obtained.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05998647
Source datasetuspto-grants-1999_12
ORD IDord-2269e35aa13441d99ff26f41432a4610
Source noteuspto-grants-1999_12