Thiophenol → HCID 18470180, compound

HRID 611666Notes

Reaction equation

HRID 611666 reaction equation
[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]Br.O(CCCCCCCBr)C1C=CC=CC=1>>[C:1]1([S:7][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][Br:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 3

HCID 7969ThiophenolHCID 783091,7-DibromoheptaneHCID 105162527-Phenoxyheptyl bromide

Product 1

HCID 18470180HCID 18470180, compoundYield 46%

Procedure

7-Phenylthioheptyl bromide was prepared from thiophenol (4.40 g, 40 mmol) and 1,7-dibromoheptane (10.32 g, 40 mmol) as described above for 7-phenoxyheptyl bromide. Yield: 46% bp; 132-136° C./0.05 torr; 1H-NMR: 1.30-1.85 (m, 10 H), 2.90 (t, 2 H), 3.35 (t, 2 H), 7.25 (s, 5 H).

Sources & evidence

ORD record
ord-19b34db99280459bb0b5eded759013c2
Source dataset
uspto-grants-1999_12
Patent number
US06001869

Reaction notes

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