Stannous chloride dihydrate → HCID 70190885, compound

HRID 612614Notes

Reaction equation

HRID 612614 reaction equation
[N:1]1([CH2:6][CH2:7][O:8][C:9]2[CH:21]=[CH:20][CH:19]=[C:18]3[C:10]=2[C:11]2[C:12]([O:30][CH3:31])=[CH:13][C:14]([O:26][CH2:27][CH2:28][CH3:29])=[C:15]([N+:23]([O-])=O)[C:16]=2[C:17]3=[O:22])[CH2:5][CH2:4][CH2:3][CH2:2]1.O.O.[Cl:34][Sn]Cl>>[ClH:34].[N:1]1([CH2:6][CH2:7][O:8][C:9]2[CH:21]=[CH:20][CH:19]=[C:18]3[C:10]=2[C:11]2[C:12]([O:30][CH3:31])=[CH:13][C:14]([O:26][CH2:27][CH2:28][CH3:29])=[C:15]([NH2:23])[C:16]=2[C:17]3=[O:22])[CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

3

Reactant 2

HCID 61436Stannous chloride dihydrateHCID 70189446HCID 70189446, compound

Product 1

HCID 70190885HCID 70190885, compoundYield 33%

Procedure

5-(2-Pyrrolidinyl-ethoxy)-4-methoxy-2-propoxy-1-nitro-fluoren-9-one (0.30 g, 0.7 mmol) and stannous chloride dihydrate (1.0 g, 0.7 mmol) are reacted as described in Example 9A to give the title compound (0.10 g, 33%). m.p. 122°-124° C.

Sources & evidence

ORD record
ord-fdf730d0e6ad4d64a64417bb60c7a1cd
Source dataset
uspto-grants-1999_12
Patent number
US06004959

Reaction notes

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