Stannous chloride dihydrate → HCID 70191515, compound

HRID 612616Notes

Reaction equation

HRID 612616 reaction equation
Cl.[CH2:2]([N:4]([CH2:38][CH3:39])[CH2:5][CH2:6][O:7][CH:8]1[CH:20]=[C:19]([O:21][CH3:22])[C:18]2[C:17]3[C:12](=[CH:13][CH:14]=[CH:15][C:16]=3[O:23][CH2:24][CH2:25][N:26]([CH2:29][CH3:30])[CH2:27][CH3:28])[C:11](=[O:31])[C:10]=2[C:9]1([N+]([O-])=O)[N+:32]([O-])=O)[CH3:3].O.O.[Cl:42][Sn]Cl>>[ClH:42].[NH2:32][C:9]1[C:10]2[C:11](=[O:31])[C:12]3[C:17](=[C:16]([O:23][CH2:24][CH2:25][N:26]([CH2:29][CH3:30])[CH2:27][CH3:28])[CH:15]=[CH:14][CH:13]=3)[C:18]=2[C:19]([O:21][CH3:22])=[CH:20][C:8]=1[O:7][CH2:6][CH2:5][N:4]([CH2:38][CH3:39])[CH2:2][CH3:3]

Participants

3

Reactant 2

HCID 61436Stannous chloride dihydrateHCID 86754972HCID 86754972, compound

Product 1

HCID 70191515HCID 70191515, compound

Procedure

2,5-Bis-(2-diethylamino-ethoxy)-1-nitro-4-methoxy-1-nitro-fluoren-9-one hydrochloride (0.37 g, 0.70 mmol) and stannous chloride dihydrate (SnCl2.2H2O; 1.0 g, 0.7 mmol) are reacted as described in Example 9A to give the title compound which has the following structural formula: ##STR52##

Sources & evidence

ORD record
ord-49b6cb40233b469d9bda45e1edeabd80
Source dataset
uspto-grants-1999_12
Patent number
US06004959

Reaction notes

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