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HRID613205

反应详情

EQUATION

反应方程式

HRID 613205 的结构方程式

REACTANTS

反应物

8
结构：O=S(=O)(O)O
HCID1118

Sulfuric acid

H2O4S

结构：OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)CO
HCID5780

D-Glucitol

C6H14O6

结构：OC[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
HCID82170

L-Glucitol

C6H14O6

2 次

结构：[BH4-].[Na+]
HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O
HCID10953859

未命名化合物

结构：O=C[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
HCID10954115

L-​Glucose

C6H12O6

结构：CC1(C)O[C@H]2CO[C@@]3(COC(C)(C)O3)C(=O)[C@H]2O1
HCID11391247

L-enantiomer

C12H18O6

结构：OC[C@H](O)[C@@H]1OC[C@@H](O)[C@@H]1O
HCID67592081

未命名化合物

PRODUCTS

生成物

1
结构：OCC(O)C1OCC(O)C1O
HCID552087

1,4-Anhydrohexitol

C6H12O5

PROCEDURE

实验过程

1,4-Anhydro-D-glucitol may be prepared using the procedure disclosed in Acta Chem. Scand., B35, 441-449 (1981), whereby D-sorbitol is heated with an aqueous mineral acid such as sulfuric acid. The L-enantiomer, 1,4-anhydro-L-glucitol, may be prepared from L-glucitol by an analogous procedure. L-glucitol may be prepared by sodium borohydride reduction of L-glucose. The D and L enantiomers may simply be combined to form a 1,4-anhydro-DL-glucitol mixture.