Acetic Acid → HCID 86736397, compound

HRID 614329Notes

Reaction equation

HRID 614329 reaction equation
[C:1]([NH+:9]([O-:11])[NH2:10])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[N:4][CH:3]=1.[C:12](O)(=[O:14])[CH3:13].C(OC(=O)C)(=O)C>C(OCC)C>[C:12]([N+:9]([O-:11])([C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[N:4][CH:3]=1)[NH2:10])(=[O:14])[CH3:13]

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 7918Acetic AnhydrideHCID 21329357HCID 21329357, compound

Product 1

HCID 86736397HCID 86736397, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

A mixture of nicotinoyl hydrazine-N-oxide (25.3 g; 0.166 m), acetic acid (85 ml) and acetic anhydride (16.9 g; 0.166 m) was heated at reflux. After one hour, the reaction mixture was cooled and poured into diethylether to yield 32 g of N-acetylnicotinoylhydrazine N-oxide.

Workup

  1. temperaturewas heated
  2. temperatureat reflux
  3. temperaturethe reaction mixture was cooled

Sources & evidence

ORD record
ord-b49e261eb629456ca553c5d651bbd905
Source dataset
uspto-grants-1979_03
Patent number
US04144343

Reaction notes

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