Hydrazine hydrate (1:1) → HCID 21327244, compound

HRID 614843Notes

Reaction equation

HRID 614843 reaction equation
[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:18])([CH3:17])[CH3:16])[CH:12]=[C:11]([N+:19]([O-])=O)[C:10]=1[CH3:22])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.O.NN>[Ni].CO>[CH2:1]([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:16])([CH3:17])[CH3:18])[CH:12]=[C:11]([NH2:19])[C:10]=1[CH3:22])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

5

Reactant 2

HCID 24654Hydrazine hydrate (1:1)HCID 213273062-Methyl-3-nitro-5-tert.-butylphenyl benzyl ether

Product 1

HCID 21327244HCID 21327244, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 887MethanolSolvent

Procedure

This is obtained, by reducing 2-methyl-3-nitro-5-tert.-butylphenyl benzyl ether with hydrazine hydrate and Raney nickel in methanol, in the form of a pale brown oil.

Workup

  1. customThis is obtained

Sources & evidence

ORD record
ord-b3e86c481ec8402290bb0774f8d1e6c1
Source dataset
uspto-grants-1979_03
Patent number
US04146630

Reaction notes

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